Handbook on the Physics and Chemistry of Rare Earths by Gschneidner K.A. (ed.)

By Gschneidner K.A. (ed.)

This carrying on with authoritative sequence offers with the chemistry, fabrics technological know-how, physics and know-how of the infrequent earth parts in an built-in demeanour. each one bankruptcy is a entire up to date, severe evaluate of a selected phase of the sector. The paintings deals the researcher and graduate pupil an entire and thorough insurance of this interesting field.

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.Highly skilled authors have written every one assessment frequently at a degree compatible for complex postgraduate scholars and study employees from a number of fields. With the nice richness of data regarding references to different overview articles written from diversified issues of view, the books are an immense reference resource and may be at the cabinets of so much libraries. (Journal of utilized Crystallography)

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Handbook on the Physics and Chemistry of Rare Earths

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27 ~~ " ~...... -""" - " - - - - - - - ID2 74 70 IG,~ 3F+ 3ù; 3F - 3H+ 3F2 ~ -- ' 62 ¸ 5 ~ ' ~ ~; - 3H6 58 t O~ ' . C' a. 2 I . I 5 7 2 2 2 J 9 2 I I 11 2 13 2 15 2 Fig. 6. Energy levels of PrlII 4f26p (J~i coupling). xl 03cm-1 i 70 ...... 3p 2 I 60 5 3p ~ 58 56 ~ 7 o / 7' " ù . ~7 3~ 54 s2 50 7 3P1 48, 46i I J= I I l 3 s 2 2 2 7 -~ ,3P o Z 9 2 2 1_~ 2 Fig. 7. Energy levels 4fl36s6p (JiJ2 coupling). B. 7 shows the Grotrian diagram of YblI 4fJ~ 6s6p(l'3Ph), J as an example of J1J2 coupling.

91) and gk = N ~ (-1) SI+S I '(l N (a,S,L,){]l N - I(äS£)lS,L,)(l N r t N - 1(äg£)lS,L,I}! B. 1. Conjugate configurations of the type (nl)4t+2-Nn'l' (a) Direct part For (nl)41+2-Nn'l', the direct part of the electrostatic interaction between the core electrons (nl) 4~+2-N and the outer electron nT is equal in magnitude and opposite in sign to the direct part of this interaction for (nl)UnT. 77). B. 93) This means that the exchange interaction is different from zero only for singlets, and among the singlets, only for those having L = k.

The energies of the terms of maximum multiplicity of fN as multiples of E 3. 91) and gk = N ~ (-1) SI+S I '(l N (a,S,L,){]l N - I(äS£)lS,L,)(l N r t N - 1(äg£)lS,L,I}! B. 1. Conjugate configurations of the type (nl)4t+2-Nn'l' (a) Direct part For (nl)41+2-Nn'l', the direct part of the electrostatic interaction between the core electrons (nl) 4~+2-N and the outer electron nT is equal in magnitude and opposite in sign to the direct part of this interaction for (nl)UnT. 77). B. 93) This means that the exchange interaction is different from zero only for singlets, and among the singlets, only for those having L = k.

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