Alkali-ion Batteries by Dongfang Yang

By Dongfang Yang

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Liu, S. Y. Zheng, K. Xu, L. B. Hu, C. S. Wang. Electrospun Sb/C Fibers for a Stable and Fast Sodium-Ion Battery Anode. ACS Nano 7 (2013) 6378. Chapter 2 Capacity Optimization Nanotechnologies for Enhanced Energy Storage Systems Natasha Ross and Emmanuel I. 5772/62319 Abstract Rechargeable lithium-ion battery (LIB) cathodes consist of transition metal oxide material, which reversibly (de)intercalates lithium at a high potential difference versus a carbon anode. Manganese oxide cathode material offers lower cost and toxicity than the normally used cobalt.

Commun. 11 (2009) 795 [67] D. H. Teng, Y. H. Yu, P. W. Li, X. Bai. A topographically triplex-roughened Ti3O5/ TiP2O7@MPCNFs hierarchical nanocomposite delivering synergistic lithium storage. RSC Adv. 3 (2013) 14237. [68] ] W. Li, M. Li, M. Wang, L. Zeng, Y. Yu. Electrospinning with partially carbonization in air: Highly porous carbon nanofibers optimized for high-performance flexible lithium-ion batteries. Nano Energy 13 (2015) 693. [69] ] L. Wang, C. X. Ding, L. C. Zhang, H. W. Xu, D. W. Zhang, T.

The main diffraction peaks of cubic spinel LiMn2O4 phase, such as (111), (311), and (400), is well developed. 2600 Å. The ionic radius of Mn4+ is smaller than that of Mn3+. Therefore, the decrease of lattice constant is indicative of an increase in Mn4+ ion concentration in the spinel [23]. The smaller MnO6 octahedra suggest a stable MnO6 framework and lower activation energy, which supports high rate electrochemical cycling [24]. Concomitantly, the coated samples with almost the same structure as LiMn2O4 support easy Li+ diffusion during the charge-discharge process.

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