By Dongfang Yang
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Liu, S. Y. Zheng, K. Xu, L. B. Hu, C. S. Wang. Electrospun Sb/C Fibers for a Stable and Fast Sodium-Ion Battery Anode. ACS Nano 7 (2013) 6378. Chapter 2 Capacity Optimization Nanotechnologies for Enhanced Energy Storage Systems Natasha Ross and Emmanuel I. 5772/62319 Abstract Rechargeable lithium-ion battery (LIB) cathodes consist of transition metal oxide material, which reversibly (de)intercalates lithium at a high potential difference versus a carbon anode. Manganese oxide cathode material offers lower cost and toxicity than the normally used cobalt.
Commun. 11 (2009) 795  D. H. Teng, Y. H. Yu, P. W. Li, X. Bai. A topographically triplex-roughened Ti3O5/ TiP2O7@MPCNFs hierarchical nanocomposite delivering synergistic lithium storage. RSC Adv. 3 (2013) 14237.  ] W. Li, M. Li, M. Wang, L. Zeng, Y. Yu. Electrospinning with partially carbonization in air: Highly porous carbon nanofibers optimized for high-performance flexible lithium-ion batteries. Nano Energy 13 (2015) 693.  ] L. Wang, C. X. Ding, L. C. Zhang, H. W. Xu, D. W. Zhang, T.
The main diffraction peaks of cubic spinel LiMn2O4 phase, such as (111), (311), and (400), is well developed. 2600 Å. The ionic radius of Mn4+ is smaller than that of Mn3+. Therefore, the decrease of lattice constant is indicative of an increase in Mn4+ ion concentration in the spinel . The smaller MnO6 octahedra suggest a stable MnO6 framework and lower activation energy, which supports high rate electrochemical cycling . Concomitantly, the coated samples with almost the same structure as LiMn2O4 support easy Li+ diffusion during the charge-discharge process.